Sofia Strekalova
FRC Kazan Scientific Center of RAS, Russia
Title: Electrochemical approach to phosphorylation of aromatic compounds
Biography
Biography: Sofia Strekalova
Abstract
The synthesis of aryl phosphonates via direct phosphorylation of aromatic C-H bonds under electrochemical mild conditions is regarded as one of the most important approaches because it meets the generally accepted criteria of green
chemistry in compared to traditional approaches. We carried out a series of experiments to obtain phosphorylated aromatic compounds (benzene and its derivatives, coumarins, pyridine, etc.) under electrochemical oxidative and reductive conditions using monometallic ([CoIIbpy], [NiIIbpy], [MnIIbpy]) and bimetallic ([CoIIbpy]/[MnIIbpy], [NiIIbpy]/[MnIIbpy]) catalytic systems. Thus in a series of experiments the products of phosphorylation of aromatic compounds were obtained under electrochemical mild conditions in good yield (up to 80%) and 100% conversion of H-phosphonate.