Past and Present Research Systems of Green Chemistry

Biography

Biography: Atsushi Ohtaka

Abstract

Metal nanoparticles have attracted considerable interest in the context of green chemistry because they are efficient catalysts for organic reactions in water. Recently, we developed linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) which showed high catalytic activity for several carbon-carbon coupling reactions in water.^1-4 In the research of Hiyama coupling reaction catalyzed by PS-PdONPs,⁵ we got finding that the reaction would occur through the different mechanism from that in the case of metal complex catalyst. In general, the mechanism of the Hiyama coupling reaction involves the oxidative addition of aryl halides to Pd⁽⁰⁾ to form the organopalladium halide (Ar-Pd-X). This is followed by transmetallation with organosilanes to provide the diorganopalladium species (Ar-Pd-R), which undergoes reductive elimination, leading to carbon-carbon bond formation and regeneration of Pd⁽⁰⁾. When a Pd^(II) species was used as the catalyst, it is supposed that reduction from Pd^(II) to Pd⁽⁰⁾ must first take place to generate the catalytically active species. However, we found that PS-PdONPs (Pd^(II) species) exhibit high catalytic activity for the Hiyama coupling reaction of aryltrimethoxysilanes with a variety of bromoarenes under air in water. In contrast, no desired coupling product was obtained from the Hiyama coupling reaction using linear polystyrene-stabilized Pd nanoparticles (PS-PdNPs, Pd⁽⁰⁾ species) as a catalyst. No formation of Pd⁽⁰⁾ species was confirmed by XPS analysis of the recovered catalyst after the reaction. These data prompted us to examine the detailed mechanism of Hiyama coupling reaction in water using PS-PdONPs as a catalyst. The different reactivities of PdONPs and PdNPs will be also discussed.