Biofuel cells based on glucose electrooxidation at conducting polymer modified electrodes with palladium and platinum nanoparticles | Ziad Khalifa | The British University, Egypt |

Past and Present Research Systems of Green Chemistry

September 19-20, 2016

Emphasis on Emerging Global Trends in the Direction of Sustainability and Environmental Safety

Ziad Khalifa

The British University, Egypt

Title: Biofuel cells based on glucose electrooxidation at conducting polymer modified electrodes with palladium and platinum nanoparticles

Biography

Biography: Ziad Khalifa

Abstract

Glucose biofuel cells are considered a promising power supply with a competent long-term stability and power density. In this respect, novel modified electrodes were fabricated for biofuel cell based on electrochemical polymerization of organic monomer on glassy carbon electrodes. An investigation was carried out on the catalytic electrooxidation of glucose in alkaline media utilizing conducting polymer electrodes modified by incorporation of palladium-nanoparticles (PdNPs) and platinum-nanoparticles (PtNPs) onto poly(1,8-aminonaphthalene) (1,8-PDAN). SEM and EDX analysis depict the homogenous distribution of the metal nanoparticles onto the polymer film. The prepared Pd/PDAN/GC, Pt/PDAN/GC and Pt-Pd/PDAN/GC modified electrodes showed an excellent electroanalytical performance with an excellent operation/storage stability. The voltage response exhibited a linear relationship with increase in glucose concentration (2.0Î¼M to 25.0mM), with a sensitivity of 160 Î¼A/mM/cm2. Higher activity and stability of Pt-Pd/PDAN/GC composite electrode were observed. These versatile kind of modified electrodes render the potential candidates for developing a new generation of glucose biofuel cells.